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#1Re:Multiwfn and wavefunction analysis»Multiwfn and NBO plots»2020-12-21 11:55:29

I've added such a file (replace -molden.txt by .molden):

ammineborane-molden.txt

It was generated via Orca/NBO7 -> *.47, then acting gennbo on the *.47 file with NBO's molden=nbo option. Mentioning "orca" in the title section of the molden file does not solve the problem.

#2Re:Multiwfn and wavefunction analysis»Multiwfn and NBO plots»2020-12-09 13:12:46

A final remark:
Multiwfn now acts fine on NBO's 31-40 files. However, for users that prefer to use the molden option in NBO's keylist, for example molden=nbo as a substitute for the *.37 file, the problem persists. Now, both Chemcraft and Multiwfn draw those wrong pictures described above.

#3Re:Multiwfn and wavefunction analysis»Multiwfn and NBO plots»2020-12-09 10:01:47

Dear Tian,

Thank you very much for solving the problem that quickly.

Best wishes,
Peter

#4Re:Multiwfn and wavefunction analysis»Multiwfn and NBO plots»2020-12-09 07:16:37

The out-file (renamed to txt due to an upload restriction) has been uploaded. The file was generated by Orca4.2.1+NBO7. The same result was obtained by NBO7 acting on the *.47 file.
Thank you for your effort.

ammineborane-tpssh-out.txt

#5Multiwfn and wavefunction analysis»Multiwfn and NBO plots»2020-12-08 17:18:46

915048960
Replies: 8

I've encountered an unexpected problem on attempts to visualize NBO-related data. As an example, two files produced by NBO7 are appended that should allow plotting NBOs for H3N-BH3 (ammineborane): ammineborane.31 and ammineborane.37 (both renamed to ...31.txt and ...37.txt to allow the upload). Orbital 3 is the N->B sigma bond and, in fact, it is correctly drawn by Chemcraft. Loading these files into Multiwfn3.7, however, produces an odd result (something like a pi-antibond). The same result is obtained by writing these files by NBO6. Other molecules show the same problem. Can anyone give a comment on the problem? Maybe there is a trivial fault caused by me, but I'm completely at a loss.

ammineborane31.txt
ammineborane37.txt

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